I had this issue too, unfortunately you cannot set your own sunset, or even better would be just pick times when you want the brightness to change! Only 3 changes would be fine like we have currently, but more would be great.
Anyways, I found a workaround that works for me. I have sensitive eyes so I like it to start getting dimmer as it is getting dark but not yet "sunset" and then even dimmer later.
I achieved this by setting the Bedtime color to be the highest at 5000K, then the Sunset to be "Incandescent" and the Daytime to be 3300K. Then I set my earliest wakeup time to 7:00 PM. By doing this I was able to adjust the graphs to something that works for me. You can set a slider to be higher than the slider above it by holding Control while you move it.
Just play around with it and I am sure you can find a setting that works for you!